The Introduction of Asymmetry into Alkyl‐Decorated Fréchet‐Type Dendrons | Zendy

Constable Edwin C. | Zendy; Graber Stefan | Zendy; Hermann B. A. | Zendy; Housecroft Catherine E. | Zendy; Malarek Michael S. | Zendy; Scherer Lukas J. | Zendy

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The Introduction of Asymmetry into Alkyl‐Decorated Fréchet‐Type Dendrons

Author(s) -

Constable Edwin C.,

Graber Stefan,

Hermann B. A.,

Housecroft Catherine E.,

Malarek Michael S.,

Scherer Lukas J.

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800134

Subject(s) - chemistry , alkyl , stereochemistry , organic chemistry , polymer chemistry , medicinal chemistry

A strategy for the introduction of asymmetry into Fréchet‐type dendrons bearing n ‐alkyl chains is described. Starting from a methyl 3,5‐dihydroxybenzoate core, 3,5‐bis(octyloxyphenyl)methoxy and 3,5‐bis(alkoxyphenyl)methoxy units are introduced in a stepwise manner. The method is illustrated by the syntheses of four representative compounds having mixed n ‐octyl/ n ‐butyl, n ‐octyl/ n ‐hexyl, n ‐octyl/ n ‐heptyl and n ‐octyl/ n ‐dodecyl substituents. The new compounds have been characterized by spectroscopic and mass spectrometric techniques. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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