Palladium‐Catalyzed Intramolecular C–O Bond Formation: An Approach to the Synthesis of Chiral Benzodioxocines | Zendy

Neogi Arpita | Zendy; Majhi Tirtha P. | Zendy; Achari Basudeb | Zendy; Chattopadhyay Partha | Zendy

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Palladium‐Catalyzed Intramolecular C–O Bond Formation: An Approach to the Synthesis of Chiral Benzodioxocines

Author(s) -

Neogi Arpita,

Majhi Tirtha P.,

Achari Basudeb,

Chattopadhyay Partha

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700762

Subject(s) - chemistry , intramolecular force , palladium , ferrocene , catalysis , aryl , derivative (finance) , combinatorial chemistry , organic chemistry , medicinal chemistry , electrochemistry , alkyl , electrode , financial economics , economics

Palladium‐catalyzed intramolecular aryl etherification using bulky binaphthylphosphane or bis(diphenylphosphanyl)ferrocene ligands is shown to be a convenient method for the synthesis of eight‐membered oxygen heterocycles. Application of this methodology to a sugar derivative led to the synthesis of chiral benzodioxocine. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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