Mild Electrochemical Deprotection of  N ‐Phenylsulfonyl  N ‐Substituted Amines Derived from ( R )‐Phenylglycinol | Zendy

Coeffard Vincent | Zendy; ThobieGautier Christine | Zendy; Beaudet Isabelle | Zendy; Le Grognec Erwan | Zendy; Quintard JeanPaul | Zendy

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Mild Electrochemical Deprotection of N ‐Phenylsulfonyl N ‐Substituted Amines Derived from ( R )‐Phenylglycinol

Author(s) -

Coeffard Vincent,

ThobieGautier Christine,

Beaudet Isabelle,

Le Grognec Erwan,

Quintard JeanPaul

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700709

Subject(s) - chemistry , electrochemistry , chemical reduction , cathodic protection , medicinal chemistry , scope (computer science) , combinatorial chemistry , organic chemistry , electrode , computer science , programming language

The electrochemical reduction of N ‐phenylsulfonyl N ‐substituted amines in a protic medium under constant cathodic potential was found to be a mild desulfonylation method, which is able to challenge the chemical ones. The influence of the nature of the N ‐substituents was considered in order to clarify the mechanistic aspects and to evaluate the scope of the method.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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