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Preparation and Structure of Oligomeric Iodosylbenzene Sulfate (PhIO) 3 ·SO 3 : Stable and Water‐Soluble Analog of Iodosylbenzene
Author(s) -
Koposov Alexey Y.,
Netzel Brian C.,
Yusubov Mekhman S.,
Nemykin Victor N.,
Nazarenko Alexander Y.,
Zhdankin Viktor V.
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200700625
Subject(s) - hypervalent molecule , chemistry , sulfate , reagent , iodobenzene , reactivity (psychology) , iodine , combinatorial chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
New phenyliodine(III) sulfate (PhIO) 3 · SO 3 , which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water‐soluble hypervalent iodine reagent with a reactivity pattern similar tothat of iodosylbenzene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)