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Unexpected Outcome in the Reaction of Triazolinedione with Carbon Nanotubes
Author(s) -
MénardMoyon Cécilia,
Gross Marius,
Bernard Maxime,
Turek Philippe,
Doris Eric,
Mioskowski Charles
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200700506
Subject(s) - chemistry , carbon nanotube , reactivity (psychology) , dimer , electron transfer , photochemistry , organic chemistry , nanotechnology , medicine , materials science , alternative medicine , pathology
The reactivity of triazolinedione (TAD) was investigated in the Diels–Alder reaction with carbon nanotubes. However, an unexpected conversion of TAD into its deaza dimer was observed. ESR spectroscopy suggested that the process was initiated by electron transfer from the nanotubes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)