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BiCl 3 ‐Catalyzed Hydroamination of Norbornene with Aromatic Amines
Author(s) -
Wei Hua,
Qian Guimin,
Xia Yuanzhi,
Li Kai,
Li Yahong,
Li Wu
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200700483
Subject(s) - hydroamination , chemistry , norbornene , catalysis , intermolecular force , organic chemistry , lewis acids and bases , combinatorial chemistry , molecule , copolymer , polymer
A BiCl 3 ‐catalyzed hydroamination reaction of norbornene, in which a variety of electron‐withdrawing groups were tolerated on amines, was presented. The current transformation possesses the advantages of being highly selective, cheap, and eco‐friendly, and this process also represents a rare system for main‐group Lewis acid catalyzed intermolecular hydroamination of unactivated alkenes.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)