Organoborane Reagents in the  C ‐Alkylation of Aromatic Aldimines | Zendy

Valpuesta María | Zendy; Muñoz Carmen | Zendy; Díaz Amelia | Zendy; Suau Rafael | Zendy; Torres Gregorio | Zendy

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Organoborane Reagents in the C ‐Alkylation of Aromatic Aldimines

Author(s) -

Valpuesta María,

Muñoz Carmen,

Díaz Amelia,

Suau Rafael,

Torres Gregorio

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700400

Subject(s) - aldimine , chemistry , reagent , imine , alkylation , aryl , borane , organic chemistry , medicinal chemistry , hydrogen peroxide , catalysis , alkyl

The reaction of an aldimine with dicyclohexylboron chloride in the presence of hydrogen peroxide gives N ‐[cyclohexyl(aryl)methyl]arylamines 2 in good yields via oxidized imine–borane complexes. The amines can also be obtained by a three‐component reaction involving an arenecarbaldehyde, an arylamine and a dialkylchloroborane reagent. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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