A Convenient Route to 2‐Hydroxy‐ and 2,15‐Dihydroxyhexahelicene | Zendy

Teplý Filip | Zendy; Stará Irena G. | Zendy; Starý Ivo | Zendy; Kollárovič Adrian | Zendy; Luštinec Daniel | Zendy; Krausová Zuzana | Zendy; Šaman David | Zendy; Fiedler Pavel | Zendy

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A Convenient Route to 2‐Hydroxy‐ and 2,15‐Dihydroxyhexahelicene

Author(s) -

Teplý Filip,

Stará Irena G.,

Starý Ivo,

Kollárovič Adrian,

Luštinec Daniel,

Krausová Zuzana,

Šaman David,

Fiedler Pavel

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700381

Subject(s) - chemistry , naphthalene , intramolecular force , benzene , benzene derivatives , organic chemistry , combinatorial chemistry , medicinal chemistry , chemical synthesis , biochemistry , in vitro

2‐Hydroxy‐ and 2,15‐dihydroxyhexahelicene were synthesised from simple benzene and naphthalene building blocks by intramolecular Co I ‐ or Ni 0 ‐catalysed [2+2+2] cycloisomerisation of CH 3 O‐substituted aromatic triynes. This approach avoids vexing photodehydrocyclisation of stilbene‐type precursors, providing thus a useful alternative to classical procedures. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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