Domino [2+2]/[2+1] and [3+2]/[2+1] Reaction Sequences of Alkynyl(alkoxy) Chromium Fischer Carbene Complexes | Zendy

PérezAnes Alexandra | Zendy; GarcíaGarcía Patricia | Zendy; SuárezSobrino Ángel Luis | Zendy; Aguilar Enrique | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Domino [2+2]/[2+1] and [3+2]/[2+1] Reaction Sequences of Alkynyl(alkoxy) Chromium Fischer Carbene Complexes

Author(s) -

PérezAnes Alexandra,

GarcíaGarcía Patricia,

SuárezSobrino Ángel Luis,

Aguilar Enrique

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700077

Subject(s) - carbene , chemistry , cyclopropanation , alkoxy group , chromium , adduct , domino , medicinal chemistry , cycloaddition , cascade reaction , acrylate , stereochemistry , organic chemistry , polymer , catalysis , monomer , alkyl

A tandem [2+2]/[2+1] sequence takes place between alkynyl(alkoxy) Fischer carbene complexes and 2,3‐dihydrofuran, producing three‐component adducts diastereoselectively in moderate yields. On the other hand, a [3+2]/[2+1] (1,3‐dipolar cycloaddition/cyclopropanation) sequence takes place between an alkynyl(alkoxy) Fischer carbene complex, trimethylsilyldiazomethane, and methyl acrylate or 2,3‐dihydrofuran. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research