Aziridinyl Vinyl Ketones from the Asymmetric Catalytic Aziridination Reaction | Zendy

Deng Yonghong | Zendy; Lee Young Rok | Zendy; Newman Cory A. | Zendy; Wulff William D. | Zendy

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Aziridinyl Vinyl Ketones from the Asymmetric Catalytic Aziridination Reaction

Author(s) -

Deng Yonghong,

Lee Young Rok,

Newman Cory A.,

Wulff William D.

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200601126

Subject(s) - synthon , chemistry , catalysis , lewis acids and bases , organic chemistry , ligand (biochemistry) , boron , asymmetric induction , enantioselective synthesis , nitroaldol reaction , carbon fibers , lewis acid catalysis , medicinal chemistry , polymer chemistry , biochemistry , materials science , receptor , composite number , composite material

Under the aegis of boron Lewis acids, prepared from either the vanol or vapol ligand, vinyl aziridinyl ketones can be obtained with a high degree of asymmetric induction from the catalytic asymmetric aziridination reaction (AZ) of imines and vinyl diazomethyl ketones. The products have potential as synthons for five‐carbon chiral amines. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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