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Indium Triflate‐Catalysed Addition of Thio Compounds to Camphene: A Novel Route to 2,3,3‐Trimethyl‐2‐thiobicyclo[2.2.1]heptane Derivatives
Author(s) -
Weïwer Michel,
Chaminade Xavier,
Bayón J. Carles,
Duñach Elisabet
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200601112
Subject(s) - camphene , chemistry , trifluoromethanesulfonate , alkene , thio , heptane , organic chemistry , umpolung , medicinal chemistry , catalysis , chromatography , essential oil , nucleophile
In III triflate‐catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)