An Imidazolium‐Based Phosphinite Ionic Liquid (IL‐OPPh 2 ) as a Reusable Reaction Medium and Pd II  Ligand in Heck Reactions of Aryl Halides with Styrene and  n ‐Butyl Acrylate | Zendy

Iranpoor Nasser | Zendy; Firouzabadi Habib | Zendy; Azadi Roya | Zendy

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An Imidazolium‐Based Phosphinite Ionic Liquid (IL‐OPPh 2 ) as a Reusable Reaction Medium and Pd II Ligand in Heck Reactions of Aryl Halides with Styrene and n ‐Butyl Acrylate

Author(s) -

Iranpoor Nasser,

Firouzabadi Habib,

Azadi Roya

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200601021

Subject(s) - chemistry , ionic liquid , heck reaction , aryl , phosphinite , styrene , ligand (biochemistry) , halide , aryl halide , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , copolymer , polymer , biochemistry , alkyl , receptor

A new imidazolium‐based phosphinite ionic liquid (IL‐OPPh 2 ) is reported as an effective reusable medium and suitable Pd II ligand for C–C bond formation through Heck coupling reactions of aryl iodides, bromides and also chlorides with styrene and n ‐butyl acrylate. The ionic liquid, still containing its corresponding Pd II complex, was easily recovered and reused in several runs without losing its efficiency.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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