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An Environmentally Friendly Oxidation System for the Selective Oxygenation of Aldimines to Oxaziridines with Anhydrous TBHP and Alumina‐Supported MoO 3 as a Recyclable Heterogeneous Catalyst
Author(s) -
Singhal Sweety,
Jain Suman L.,
Prasad V. V. D. N.,
Sain Bir
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600980
Subject(s) - anhydrous , chemistry , aldimine , catalysis , selectivity , environmentally friendly , organic chemistry , heterogeneous catalysis , oxygenation , combinatorial chemistry , ecology , biology
A highly efficient and selective protocol for the oxygenation of various aldimines to oxaziridines, which proceeds in excellent yields with enhanced selectivity by using alumina‐supported MoO 3 as a recyclable heterogeneous catalyst and anhydrous TBHP as the ultimate oxidant, is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)