Stereoselective Intramolecular Oxazine Formation by a π‐Allylpalladium Complex Catalyzed by Pd 0 | Zendy

Joo JaeEun | Zendy; Lee KeeYoung | Zendy; Pham VanThoai | Zendy; Ham WonHun | Zendy

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Stereoselective Intramolecular Oxazine Formation by a π‐Allylpalladium Complex Catalyzed by Pd 0

Author(s) -

Joo JaeEun,

Lee KeeYoung,

Pham VanThoai,

Ham WonHun

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600927

Subject(s) - chemistry , palladium , intramolecular force , benzamide , catalysis , stereoselectivity , oxazines , medicinal chemistry , stereochemistry , organic chemistry

An efficient procedure for synthesizing oxazines was developed by the palladium(0)‐catalyzed intramolecular cyclization of a benzamide through a π‐allylpalladium(II) complex. Unlike other palladium‐catalyzed reactions, the temperature was found to be a key factor in determining the stereochemistry of the oxazine. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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