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Transient Amino‐Hydrazino‐Carbenes: A Radical Pathway for Intramolecular 1,2‐Migration Reactions
Author(s) -
Cattoën Xavier,
Gornitzka Heinz,
Tham Fook S.,
Miqueu Karinne,
Bourissou Didier,
Bertrand Guy
Publication year - 2007
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600901
Subject(s) - chemistry , intramolecular force , transient (computer programming) , radical , intramolecular reaction , stereochemistry , photochemistry , computational chemistry , organic chemistry , computer science , operating system
The transient amino‐hydrazino‐carbenes 2c – e are reported to undergo intramolecular 1,2‐migration reactions that proceed through a radical pathway according to DFT calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)