N ‐Functionalization of Azoles through Coupling Reactions with Alkoxydienyl and Alkoxystyryl Boronic Esters | Zendy

Deagostino Annamaria | Zendy; Prandi Cristina | Zendy; Zavattaro Chiara | Zendy; Venturello Paolo | Zendy

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N ‐Functionalization of Azoles through Coupling Reactions with Alkoxydienyl and Alkoxystyryl Boronic Esters

Author(s) -

Deagostino Annamaria,

Prandi Cristina,

Zavattaro Chiara,

Venturello Paolo

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600872

Subject(s) - chemistry , surface modification , boronic acid , coupling reaction , copper , combinatorial chemistry , coupling (piping) , regioselectivity , organic chemistry , catalysis , mechanical engineering , engineering

Alkoxydienyl boronates 1a and 1b and alkoxystyryl boronate 2 have been used in various copper mediated cross‐coupling reactions with azoles. A variety of N ‐alkoxydienyl‐ and N ‐styrylazoles have been synthesized under mild conditions. The process utilizes Cu(OAc) 2 in the presence of CsF in CH 2 Cl 2 at room temperature. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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