Uncommon 5‐Methoxyisoflavans from  Desmodium canum | Zendy

de Andrade Lima Cláudia Sampaio | Zendy; Zappia Giovanni | Zendy; Delle Monache Giuliano | Zendy; Botta Bruno | Zendy

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Uncommon 5‐Methoxyisoflavans from Desmodium canum

Author(s) -

de Andrade Lima Cláudia Sampaio,

Zappia Giovanni,

Delle Monache Giuliano,

Botta Bruno

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600742

Subject(s) - desmodium , chemistry , substituent , hexane , stereochemistry , organic chemistry , traditional medicine , medicine

Bioactive minor components of the hexane extract of Desmodium canum root have been assigned the new structures 2 – 7 of complex isoflavans. Four of them contain the 6‐methyl group typical of the major isoflavanone plant constituents and were named desmodians A–C and 3′‐hydroxydesmodian C, the others being 6‐desmethyldesmodians A and B. All of the isoflavans except 6 (with a 5‐OH group) carry a quite rare 5‐OMe substituent. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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