Investigating Direct Alkynylation at the Bridgehead of Bicyclic Cages Using Silver(I) Acetylides | Zendy

Pouwer Rebecca H. | Zendy; Harper Jason B. | Zendy; Vyakaranam Kamesh | Zendy; Michl Josef | Zendy; Williams Craig M. | Zendy; Jessen Carsten H. | Zendy; Bernhardt Paul V. | Zendy

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Investigating Direct Alkynylation at the Bridgehead of Bicyclic Cages Using Silver(I) Acetylides

Author(s) -

Pouwer Rebecca H.,

Harper Jason B.,

Vyakaranam Kamesh,

Michl Josef,

Williams Craig M.,

Jessen Carsten H.,

Bernhardt Paul V.

Publication year - 2007

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600701

Subject(s) - chemistry , bicyclic molecule , alkynylation , substrate (aquarium) , adamantane , carbon fibers , stereochemistry , combinatorial chemistry , organic chemistry , medicinal chemistry , catalysis , oceanography , materials science , composite number , composite material , geology

Silver(I) acetylides facilitate direct carbon–carbon bond formation at the bridgehead position of adamantane, and in some instances related systems such as carborate anions and bicyclo[2.2.2]octanes. Substrate constraints along with attempts to further understand the underlying mechanism are presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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