Rhodium‐Catalyzed Hydroboration Reactions with Sulfur and Nitrogen Analogues of Catecholborane | Zendy

Hadebe Siphamandla W. | Zendy; Robinson Ross S. | Zendy

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Rhodium‐Catalyzed Hydroboration Reactions with Sulfur and Nitrogen Analogues of Catecholborane

Author(s) -

Hadebe Siphamandla W.,

Robinson Ross S.

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600564

Subject(s) - chemistry , hydroboration , rhodium , sulfur , disproportionation , catalysis , nitrogen , organic chemistry , catechol

Rhodium‐catalyzed hydroboration of 1‐octene and trans ‐4‐octene with sulfur‐ and nitrogen analogues of catecholborane are demonstrated with the use of in situ 11 B NMR spectroscopy. Our study shows that the sulfur‐ and nitrogen analogues are significantly less prone to disproportionation than catechol, which results in enhanced yields of the desired compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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