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Highly Regioselective Rhenium‐Catalyzed Hydrosilylation of Styrenes
Author(s) -
Zhao WenGuo,
Hua Ruimao
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600555
Subject(s) - markovnikov's rule , chemistry , regioselectivity , hydrosilylation , silanes , catalysis , rhenium , toluene , organic chemistry , adduct , silane
Abstract The addition reaction of silanes to styrenes is efficiently catalyzed by ReBr(CO) 5 in toluene heated at 120 °C and selectively affords anti ‐Markovnikov adducts in good to high yields. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)