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Carbodiazenylation of Olefins by Radical Iodine Transfer and Addition to Arenediazonium Salts
Author(s) -
Blank Olga,
Heinrich Markus R.
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600528
Subject(s) - chemistry , iodine , organic chemistry , diazonium compounds , polymer chemistry
Carbodiazenylation of olefins can be achieved with arenediazonium salts under reductive conditions. The method can be extended to aliphatic substituents when iodine compounds are present in the reaction mixture. Incorporation is achieved through a radical iodine transfer. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)