RhCl(PPh 3 ) 3 /DPPF: A Useful and Efficient Catalyst for Cross‐Coupling Reactions of Activated Alkenyl Tosylates with Arylboronic Acids | Zendy

Wu Jie | Zendy; Zhang Liang | Zendy; Gao Ke | Zendy

Premium

RhCl(PPh 3 ) 3 /DPPF: A Useful and Efficient Catalyst for Cross‐Coupling Reactions of Activated Alkenyl Tosylates with Arylboronic Acids

Author(s) -

Wu Jie,

Zhang Liang,

Gao Ke

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600469

Subject(s) - chemistry , rhodium , catalysis , furan , coumarin , organic chemistry , suzuki reaction , combinatorial chemistry , palladium

A useful and effective rhodium catalyst system – [RhCl(PPh 3 ) 3 /DPPF] – for the Suzuki–Miyaura cross‐coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium‐catalyzed Suzuki–Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product‐like compounds, such as furan‐2(5 H )‐one, coumarin, pyrone, and quinolin‐2(1 H )‐one derivatives.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research