A New, Mild, General and Efficient Route to Aryl Ethyl Carbonates in Solvent‐Free Conditions Promoted by Magnesium Perchlorate | Zendy

Bartoli Giuseppe | Zendy; Bosco Marcella | Zendy; Carlone Armando | Zendy; Locatelli Manuela | Zendy; Marcantoni Enrico | Zendy; Melchiorre Paolo | Zendy; Palazzi Paolo | Zendy; Sambri Letizia | Zendy

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A New, Mild, General and Efficient Route to Aryl Ethyl Carbonates in Solvent‐Free Conditions Promoted by Magnesium Perchlorate

Author(s) -

Bartoli Giuseppe,

Bosco Marcella,

Carlone Armando,

Locatelli Manuela,

Marcantoni Enrico,

Melchiorre Paolo,

Palazzi Paolo,

Sambri Letizia

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600366

Subject(s) - chemistry , aryl , perchlorate , magnesium , lewis acids and bases , alkyl , organic chemistry , solvent , activator (genetics) , catalysis , ion , biochemistry , gene

A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO 4 ) 2 , a specific activator of 1,3‐dicarbonyl compounds, and shows general applicability. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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