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A New, Mild, General and Efficient Route to Aryl Ethyl Carbonates in Solvent‐Free Conditions Promoted by Magnesium Perchlorate
Author(s) -
Bartoli Giuseppe,
Bosco Marcella,
Carlone Armando,
Locatelli Manuela,
Marcantoni Enrico,
Melchiorre Paolo,
Palazzi Paolo,
Sambri Letizia
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600366
Subject(s) - chemistry , aryl , perchlorate , magnesium , lewis acids and bases , alkyl , organic chemistry , solvent , activator (genetics) , catalysis , ion , biochemistry , gene
A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO 4 ) 2 , a specific activator of 1,3‐dicarbonyl compounds, and shows general applicability. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)