Premium
Metal‐Catalyzed Bond Reorganization of 1,3‐Diynes
Author(s) -
Cho Eun Jin,
Kim Mansuk,
Lee Daesung
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600332
Subject(s) - chemistry , heteroatom , carbene , catalysis , metal , platinum , medicinal chemistry , photochemistry , stereochemistry , organic chemistry , ring (chemistry)
1,3‐Diynes possessing propargylic heteroatom substituents provide functionalized 1,5‐dien‐3‐ynes when catalyzed by platinum and gold. This rearrangement implies the involvement of metallotropic [1,3]‐shift of the intermediate alkynyl metal carbene species. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom