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Metal‐Catalyzed Bond Reorganization of 1,3‐Diynes
Author(s) -
Cho Eun Jin,
Kim Mansuk,
Lee Daesung
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600332
Subject(s) - chemistry , heteroatom , carbene , catalysis , metal , platinum , medicinal chemistry , photochemistry , stereochemistry , organic chemistry , ring (chemistry)
1,3‐Diynes possessing propargylic heteroatom substituents provide functionalized 1,5‐dien‐3‐ynes when catalyzed by platinum and gold. This rearrangement implies the involvement of metallotropic [1,3]‐shift of the intermediate alkynyl metal carbene species. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)