A New Efficient Synthesis of Long‐Chain Di‐ and Triaminopolyols | Zendy

Coste Gérald | Zendy; GerberLemaire Sandrine | Zendy

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A New Efficient Synthesis of Long‐Chain Di‐ and Triaminopolyols

Author(s) -

Coste Gérald,

GerberLemaire Sandrine

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600276

Subject(s) - chemistry , polyketide , amine gas treating , surface modification , combinatorial chemistry , chain (unit) , stereochemistry , enantioselective synthesis , long chain , organic chemistry , polymer science , catalysis , biosynthesis , physics , astronomy , enzyme

The asymmetric synthesis of long‐chain di‐ and triaminopolyols is reported. The developed methodology is based on the functionalization of 3,3′‐methylenebis{[6‐(benzyloxy)methoxy]cyclohept‐3‐en‐1‐ol} derivatives that allows theselective introduction of amine moieties at defined positions of polyketide fragments. The versatile strategy disclosed here requires few purification steps and may generate a large panel of stereoisomers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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