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C 70 [NR 2 ] 2 O: The First C 70 Intramolecular Ethers Bearing Two Amine Groups
Author(s) -
Troshina Olesya A.,
Troshin Pavel A.,
Peregudov Alexander S.,
Kozlovski Viacheslav I.,
Lyubovskaya Rimma N.
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600264
Subject(s) - chemistry , intramolecular force , ether , yield (engineering) , amine gas treating , fullerene , medicinal chemistry , stereochemistry , polymer chemistry , organic chemistry , materials science , metallurgy
Photochemical reactions between [70]fullerene and N ‐substituted piperazines yield C 70 [NR 2 ] 2 O, the first isolated and characterized C 70 ‐based aminofullerenes. Spectroscopic characterization revealed the presence of intramolecular ether moieties in the structures of these compounds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)