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Rigid Bisphenanthrolines: Synthesis, Structure and Self‐Assembly at a Solid–Liquid Interface
Author(s) -
Schmittel Michael,
Kalsani Venkateshwarlu,
Jäckel Frank,
Rabe Jürgen P.,
Bats Jan W.,
Fenske Dieter
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600174
Subject(s) - chemistry , scanning tunneling microscope , monolayer , self assembly , solid state , interface (matter) , nanotechnology , self assembled monolayer , crystallography , stereochemistry , molecule , organic chemistry , biochemistry , gibbs isotherm , materials science
Several rigid linear bisphenanthrolines with and without bulky groups at the bisimine sites were synthesized. For three representatives, the solid‐state structures were elucidated. Their potential for self‐assembled monolayers was explored by scanning tunneling microscopy (STM) at the solid–liquid interface, and the resulting architectures were found to be promising candidates for templating metal‐ion nanopatterns. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)