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Intermolecular [4+2] Cycloadditions of a Reactive Cyclopentadienone
Author(s) -
Harmata Michael,
Gomes Maria G.
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600173
Subject(s) - chemistry , stereoselectivity , yield (engineering) , intermolecular force , reactive intermediate , organic chemistry , computational chemistry , molecule , catalysis , thermodynamics , physics
A reactive cyclopentadienone gives Diels–Alder cycloadducts with a variety of dienes in high yield and often with extremely high levels of regio‐ and stereoselectivity. The high degree of generality of this reaction suggests it will be of use in organic synthesis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)