Enantiodifferentiation of Aliphatic Ethers by the Dirhodium Method | Zendy

Díaz Gómez Edison | Zendy; Albert Dieter | Zendy; Duddeck Helmut | Zendy; Kozhushkov Sergei I. | Zendy; de Meijere Armin | Zendy

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Enantiodifferentiation of Aliphatic Ethers by the Dirhodium Method

Author(s) -

Díaz Gómez Edison,

Albert Dieter,

Duddeck Helmut,

Kozhushkov Sergei I.,

de Meijere Armin

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600137

Subject(s) - chemistry , enantiomer , nuclear magnetic resonance spectroscopy , ligand (biochemistry) , organic chemistry , stereochemistry , medicinal chemistry , receptor , biochemistry

The enantiomers of chiral aliphatic ethers can easily bedifferentiated by the dirhodium method, i.e. by 1 H and 13 C NMR spectroscopy in the presence of the chiral auxiliary Rh 2 [(+)‐MTPA] 4 . This is the first direct chiral recognitionby spectroscopic methods in this class of ligand compounds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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