Unusual Fluoroalkenylation of Porphyrins: A Highly Stereoselective Synthesis of 10,20‐Diaryl‐5‐[( E )‐fluoroalkenyl]‐15‐(fluoroalkyl)porphyrins | Zendy

Jin LiMei | Zendy; Yin JuanJuan | Zendy; Chen Liang | Zendy; Xiao JiChang | Zendy; Guo CanCheng | Zendy; Chen QingYun | Zendy

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Unusual Fluoroalkenylation of Porphyrins: A Highly Stereoselective Synthesis of 10,20‐Diaryl‐5‐[( E )‐fluoroalkenyl]‐15‐(fluoroalkyl)porphyrins

Author(s) -

Jin LiMei,

Yin JuanJuan,

Chen Liang,

Xiao JiChang,

Guo CanCheng,

Chen QingYun

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600130

Subject(s) - chemistry , stereoselectivity , intramolecular force , toluene , porphyrin , free base , medicinal chemistry , base (topology) , polymer chemistry , organic chemistry , stereochemistry , catalysis , mathematical analysis , salt (chemistry) , mathematics

A series of 10,20‐diaryl‐5‐[( E )‐fluoroalkenyl]‐15‐(fluoroalkyl)porphyrins has been synthesized by the reaction of free‐base 5,15‐diarylporphyrins with fluoroalkyl iodides in the presence of Na 2 S 2 O 4 . Subsequent intramolecular cyclization of the corresponding (fluoroalkenyl)porphyrins occurs smoothly in refluxing toluene/H 2 O. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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