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Indium Triflate Catalyzed Rearrangement of Aryl‐Substituted Cyclopropyl Carbinols to 1,4‐Disubstituted 1,3‐Butadienes
Author(s) -
Ranu Brindaban C.,
Banerjee Subhash
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200600037
Subject(s) - chemistry , dichloromethane , aryl , trifluoromethanesulfonate , stereoselectivity , conjugated system , catalysis , medicinal chemistry , indium , organic chemistry , solvent , alkyl , polymer
Aryl‐substituted cyclopropyl carbinol derivatives undergo a facile stereoselective rearrangement catalyzed by In(OTf) 3 in dichloromethane under sonication to produce the substituted conjugated all ‐ trans ‐butadienes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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