A Second‐Generation Dendrimer with Six 2,9‐Dimethyl‐1,10‐phenanthroline Units as Ligand for Copper‐Catalyzed Reactions | Zendy

Lüning Ulrich | Zendy; Eggert Jan P. W. | Zendy; Hagemann Kathrin | Zendy

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A Second‐Generation Dendrimer with Six 2,9‐Dimethyl‐1,10‐phenanthroline Units as Ligand for Copper‐Catalyzed Reactions

Author(s) -

Lüning Ulrich,

Eggert Jan P. W.,

Hagemann Kathrin

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200600033

Subject(s) - chemistry , dendrimer , random hexamer , trimer , aryl , copper , phenanthroline , ligand (biochemistry) , ether , catalysis , polymer chemistry , stereochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , crystallography , dimer , receptor , biochemistry , alkyl

2,9‐Dimethyl‐1,10‐phenanthroline (neocuproine, 1 ) has been attached to dendritic structures through its 5‐position providing a trimer 7 and the hexamers 11 and 12 . The copper‐binding capability of the hexamer 12 has been studied, and the 6:1 complex has been used to catalyze the Cu + ‐promoted substitution of an iodoarene 14 to give an aryl ether 15 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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