Oxidation of Alcohols and  vic ‐Diols with H 2 O 2  by Using Catalytic Amounts of  N ‐Methylpyrrolidin‐2‐one Hydrotribromide | Zendy

Joseph Jomy K. | Zendy; Jain Suman L. | Zendy; Sain Bir | Zendy

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Oxidation of Alcohols and vic ‐Diols with H 2 O 2 by Using Catalytic Amounts of N ‐Methylpyrrolidin‐2‐one Hydrotribromide

Author(s) -

Joseph Jomy K.,

Jain Suman L.,

Sain Bir

Publication year - 2006

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200500758

Subject(s) - chemistry , hydrogen peroxide , catalysis , acetonitrile , aqueous solution , alcohol oxidation , organic chemistry , primary (astronomy) , homogeneous catalysis , medicinal chemistry , physics , astronomy

A variety of secondary alcohols, 1,2‐diols and primary alcohols were selectively oxidized in excellent yields to their corresponding ketones, 1,2‐diketones and aldehydes with aqueous 30 % hydrogen peroxide in refluxing acetonitrile in the presence of catalytic amounts of N ‐methylpyrrolidin‐2‐one hydrotribromide (MPHT). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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