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β‐Arylthio‐α‐chloroalkyl Ethers — Novel 1,1‐Bis‐electrophiles for Geminal Alkylation
Author(s) -
Gromov Alexey V.,
Smit William A.
Publication year - 2006
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200500689
Subject(s) - geminal , chemistry , alkylation , electrophile , adduct , organic chemistry , medicinal chemistry , catalysis
A novel protocol for geminal alkylation is suggested based upon the consecutive generation of two cationoid intermediates from the easily prepared adducts of arylsulfenyl chlorides and vinyl ethers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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