Dimethyldioxirane and Acetone Are Not in Equilibrium | Zendy

Zeller KlausPeter | Zendy; Kowallik Meike | Zendy; Schuler Paul | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Dimethyldioxirane and Acetone Are Not in Equilibrium

Author(s) -

Zeller KlausPeter,

Kowallik Meike,

Schuler Paul

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200500554

Subject(s) - dimethyldioxirane , dioxirane , chemistry , acetone , carbonyl group , ketone , oxygen atom , nuclear magnetic resonance spectroscopy , methylcyclopentane , organic chemistry , medicinal chemistry , catalysis , selectivity , molecule

The potential transfer of an oxygen atom from dioxiranes to a ketonic carbonyl group is disproved by appropriate D‐ and 13 C‐labelling. As shown by 13 C NMR spectroscopy bis(trideuteriomethyl)dioxirane and [carbonyl‐ 13 C]acetone are not in equilibrium with [D 6 ]acetone and [3‐ 13 C]dimethyldioxirane. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research