Simple 1,2‐Diamine Ligands for Asymmetric Addition of Aryllithium Reagents to Imines | Zendy

Cabello Noemi | Zendy; Kizirian JeanClaude | Zendy; Gille Ségolène | Zendy; Alexakis Alexandre | Zendy; Bernardinelli Gérald | Zendy; Pinchard Laurent | Zendy; Caille JeanClaude | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Simple 1,2‐Diamine Ligands for Asymmetric Addition of Aryllithium Reagents to Imines

Author(s) -

Cabello Noemi,

Kizirian JeanClaude,

Gille Ségolène,

Alexakis Alexandre,

Bernardinelli Gérald,

Pinchard Laurent,

Caille JeanClaude

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200500447

Subject(s) - chemistry , enantioselective synthesis , reagent , enantiomer , diamine , enantiomeric excess , combinatorial chemistry , organic chemistry , catalysis

Enantioselective addition of various aryllithium reagents to aromatic imines was catalyzed (20 mol‐%) by readily accessible 1,2‐diamines to afford a wide range of protected diarylmethylamines in up to 94 % enantiomeric excess. Furthermore, the absolute configuration of these arylation products was determined by using X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research