Brønsted Acid Mediated Double Friedel–Crafts Reaction of Methylenecyclopropanes with Arenes | Zendy

Wang BaoYu | Zendy; Jiang RiShan | Zendy; Li Jia | Zendy; Shi Min | Zendy

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Brønsted Acid Mediated Double Friedel–Crafts Reaction of Methylenecyclopropanes with Arenes

Author(s) -

Wang BaoYu,

Jiang RiShan,

Li Jia,

Shi Min

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200500261

Subject(s) - chemistry , friedel–crafts reaction , brønsted–lowry acid–base theory , deuterium , reaction conditions , organic chemistry , reaction mechanism , catalysis , physics , quantum mechanics

This paper describes the Brønsted acid mediated reaction of methylenecyclopropanes with various arenes to give the corresponding double Friedel–Crafts reaction products (cyclized products) under mild conditions. A plausible reaction mechanism is discussed on the basis of deuterium labeling and control experiments. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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