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First Lewis Acid Catalyzed Generation and Reaction of α‐Organylsulfanyl and α‐Organylselanyl Carbenium Ions Using Ethyl α‐Fluoroacetate Derivatives
Author(s) -
Yoshimatsu Mitsuhiro,
Kawamoto Masayo,
Gotoh Kohei
Publication year - 2005
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200500179
Subject(s) - chemistry , fluoroacetate , lewis acids and bases , scandium , trifluoromethanesulfonate , nucleophile , catalysis , lewis acid catalysis , medicinal chemistry , organic chemistry , biochemistry
Lewis acid catalyzed generation and reactions of α‐organylsulfanyl and α‐organylselanyl carbenium ions with nucleophiles proceeded in high yields using α‐fluoro‐α‐organylsulfanyl‐ and α‐fluoro‐α‐organylselanylacetate and 5 mol‐% scandium triflate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)