First Lewis Acid Catalyzed Generation and Reaction of α‐Organylsulfanyl and α‐Organylselanyl Carbenium Ions Using Ethyl α‐Fluoroacetate Derivatives | Zendy

Yoshimatsu Mitsuhiro | Zendy; Kawamoto Masayo | Zendy; Gotoh Kohei | Zendy

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First Lewis Acid Catalyzed Generation and Reaction of α‐Organylsulfanyl and α‐Organylselanyl Carbenium Ions Using Ethyl α‐Fluoroacetate Derivatives

Author(s) -

Yoshimatsu Mitsuhiro,

Kawamoto Masayo,

Gotoh Kohei

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200500179

Subject(s) - chemistry , fluoroacetate , lewis acids and bases , scandium , trifluoromethanesulfonate , nucleophile , catalysis , lewis acid catalysis , medicinal chemistry , organic chemistry , biochemistry

Lewis acid catalyzed generation and reactions of α‐organylsulfanyl and α‐organylselanyl carbenium ions with nucleophiles proceeded in high yields using α‐fluoro‐α‐organylsulfanyl‐ and α‐fluoro‐α‐organylselanylacetate and 5 mol‐% scandium triflate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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