Premium
Artificial Epoxidase II. Synthesis of Cyclodextrin Ketoesters and Epoxidation of Alkenes
Author(s) -
Rousseau Cyril,
Christensen Brian,
Bols Mikael
Publication year - 2005
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200500034
Subject(s) - chemistry , cyclodextrin , yield (engineering) , catalysis , organic chemistry , combinatorial chemistry , metallurgy , materials science
Four cyclodextrin ketones were synthesised and investigated as epoxidation catalysts. In the presence of oxone they catalysed the epoxidation of mono‐, di‐ and trisubstituted alkenes in 17–100 % yield and 0–45 % ee . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)