Premium
Dihydroaromatic Boronic Esters as Building Blocks for the Synthesis of Phenanthrenes and Phenanthridines
Author(s) -
Hilt Gerhard,
Hess Wilfried,
Schmidt Frank
Publication year - 2005
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200500025
Subject(s) - chemistry , phenanthrenes , phenanthridine , phenanthrene , cobalt , palladium , catalysis , organic chemistry , regioselectivity , combinatorial chemistry
Abstract Alkenyl‐substituted dihydroaromatic boronic esters, generated by neutral cobalt( I )‐catalysed Diels–Alder reactions, reacted under palladium catalysis conditions with diiodobenzene, bromoiodobenzene and iodoaniline derivatives for the synthesis of regioselectively substituted phenanthrene and phenanthridine derivatives. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)