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Enzyme‐Catalysed Transformations of ent ‐Kaurane Diterpenoids
Author(s) -
Monsalve Leandro N.,
Rosselli Sergio,
Bruno Maurizio,
Baldessari Alicia
Publication year - 2005
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200400862
Subject(s) - chemistry , acetylation , stereoselectivity , enzyme , stereochemistry , organic chemistry , catalysis , biochemistry , gene
Several acetyl derivatives of linearol, atractyligenin and atractylitriol were obtained through enzyme‐catalysed acetylation and deacetylation reactions. In most reactions lipases showed regio‐ and stereoselective behaviour, allowing a family of novel compounds to be prepared. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)