Fluorinations of α‐Seleno Carboxylic Acid Derivatives with Hypervalent (Difluoroiodo)toluene | Zendy

Arrica Maria A. | Zendy; Wirth Thomas | Zendy

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Fluorinations of α‐Seleno Carboxylic Acid Derivatives with Hypervalent (Difluoroiodo)toluene

Author(s) -

Arrica Maria A.,

Wirth Thomas

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400659

Subject(s) - chemistry , toluene , hypervalent molecule , fluorine , chlorine , organic chemistry , elemental analysis , acceptor , iodine , physics , condensed matter physics

A very efficient synthesis of (difluoroiodo)toluene avoiding the use of elemental chlorine and elemental fluorine is described. We have fluorinated a series of α‐acceptor substituted selenides using (difluoroiodo)toluene. The reactions are usually very clean and under the reaction conditions no further oxidized products are observed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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