Reactions of  gem ‐Aryl‐Disubstituted Methylenecyclopropanes with Diaryl Diselenide in the Presence of Iodosobenzene Diacetate | Zendy

Shi Min | Zendy; Wang BaoYu | Zendy; Li Jia | Zendy

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Reactions of gem ‐Aryl‐Disubstituted Methylenecyclopropanes with Diaryl Diselenide in the Presence of Iodosobenzene Diacetate

Author(s) -

Shi Min,

Wang BaoYu,

Li Jia

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400644

Subject(s) - chemistry , diselenide , aryl , diphenyl diselenide , medicinal chemistry , ring (chemistry) , organic chemistry , selenium , alkyl

The reaction of gem ‐aryl‐disubstituted methylenecyclopropanes 1 with diaryl diselenide produced the corresponding ring‐opened products 1,2‐bis(arylselanyl)‐3,3‐diarylcyclobut‐1‐ene 4 in the presence of iodosobenzene diacetate in moderate‐to‐good yields under mild conditions. The further transformation of 4 in the presence of MCPBA has also been examined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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