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Reactions of gem ‐Aryl‐Disubstituted Methylenecyclopropanes with Diaryl Diselenide in the Presence of Iodosobenzene Diacetate
Author(s) -
Shi Min,
Wang BaoYu,
Li Jia
Publication year - 2005
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200400644
Subject(s) - chemistry , diselenide , aryl , diphenyl diselenide , medicinal chemistry , ring (chemistry) , organic chemistry , selenium , alkyl
The reaction of gem ‐aryl‐disubstituted methylenecyclopropanes 1 with diaryl diselenide produced the corresponding ring‐opened products 1,2‐bis(arylselanyl)‐3,3‐diarylcyclobut‐1‐ene 4 in the presence of iodosobenzene diacetate in moderate‐to‐good yields under mild conditions. The further transformation of 4 in the presence of MCPBA has also been examined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)