Synthesis of the First Chiral, Functionalised‐Bridged Resorcinarenes in Asymmetric Catalysis: Evidence for Intracavity Asymmetric Catalysis | Zendy

Arnott Gareth | Zendy; Heaney Harry | Zendy; Hunter Roger | Zendy; Page Philip C. B. | Zendy

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Synthesis of the First Chiral, Functionalised‐Bridged Resorcinarenes in Asymmetric Catalysis: Evidence for Intracavity Asymmetric Catalysis

Author(s) -

Arnott Gareth,

Heaney Harry,

Hunter Roger,

Page Philip C. B.

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400615

Subject(s) - chemistry , enantioselective synthesis , diethylzinc , catalysis , benzaldehyde , organic chemistry , organocatalysis , combinatorial chemistry

Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantioselective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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