Aquapalladium Complex: A Stable and Convenient Catalyst for the Intermolecular Hydroamination of Alkynes | Zendy

Shimada Tomohiro | Zendy; Bajracharya Gan B. | Zendy; Yamamoto Yoshinori | Zendy

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Aquapalladium Complex: A Stable and Convenient Catalyst for the Intermolecular Hydroamination of Alkynes

Author(s) -

Shimada Tomohiro,

Bajracharya Gan B.,

Yamamoto Yoshinori

Publication year - 2005

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400568

Subject(s) - hydroamination , chemistry , intermolecular force , catalysis , alkyne , medicinal chemistry , organic chemistry , combinatorial chemistry , molecule

The intermolecular hydroamination of alkynes proceeds very smoothly in the presence of a catalytic amount of the aquapalladium complex [Pd(dppe)(H 2 O) 2 ](TfO) 2 . This reaction most probably proceeds through the formation of an equilibrium between the hydroxopalladium and the amidopalladium complexes, and subsequent aminopalladation of alkynes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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