Stereo‐ and Regiocontrol in the Formation of Lactams by Rhodium‐Carbenoid C−H Insertion of α‐Diazoacetamides | Zendy

Gois Pedro M. P. | Zendy; Afonso Carlos A. M. | Zendy

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Stereo‐ and Regiocontrol in the Formation of Lactams by Rhodium‐Carbenoid C−H Insertion of α‐Diazoacetamides

Author(s) -

Gois Pedro M. P.,

Afonso Carlos A. M.

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400237

Subject(s) - carbenoid , chemistry , intramolecular force , rhodium , insertion reaction , stereochemistry , lactam , combinatorial chemistry , catalysis , organic chemistry

The dirhodium( II )‐catalysed intramolecular C−H insertion reaction of α‐diazoacetamides is a powerful methodology for the preparation of highly valuable heterocyclic compounds such as lactams. In this Microreview we present lactam formation by intramolecular C−H insertion of α‐diazoacetamides, focusing on the effects that have a profound impact on the reaction pathway. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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