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Telomerization of Butadiene with L ‐Arabinose and D ‐Xylose in DMF: Selective Formation of their Monooctadienyl Glycosides
Author(s) -
Estrine Boris,
Bouquillon Sandrine,
Hénin Françoise,
Muzart Jacques
Publication year - 2004
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200400064
Subject(s) - telomerization , chemistry , arabinose , xylose , anomer , glycoside , catalysis , substrate (aquarium) , organic chemistry , 1,3 butadiene , solvent , stereochemistry , fermentation , oceanography , geology
Conditions to achieve the palladium‐catalysed telomerization of butadiene with L ‐arabinose and D ‐xylose as telogens have been identified. With DMF as solvent, optimised ratios of substrate, reactants and catalytic system allowed the selective grafting of one octadienyl chain onto the anomeric hydroxy group. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)