Dialkylation of Various Butane‐2,3‐diacetals Using Allylsilane and 1,8‐Bis(trimethylsilyl)‐2,6‐octadiene | Zendy

Mariet Natacha | Zendy; Pellissier Hélène | Zendy; IbrahimOuali Malika | Zendy; Santelli Maurice | Zendy

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Dialkylation of Various Butane‐2,3‐diacetals Using Allylsilane and 1,8‐Bis(trimethylsilyl)‐2,6‐octadiene

Author(s) -

Mariet Natacha,

Pellissier Hélène,

IbrahimOuali Malika,

Santelli Maurice

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400042

Subject(s) - chemistry , trimethylsilyl , butane , organic chemistry , medicinal chemistry , stereochemistry , catalysis

We report in this paper a greatly improved procedure for the formation of a range of 1‐acetyl‐1‐methyl‐2,5‐divinylcyclopentanes from 1,8‐bis(trimethylsilyl)octa‐2,6‐diene (BISTRO) and 1,2‐diacetals prepared directly from biacetyl. These 1‐acetyl‐1‐methyl‐2,5‐divinylcyclopentanes are building blocks for the synthesis of 2‐ and 3‐methoxy‐12‐oxo‐17β‐vinylestranes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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