Synthesis of a Novel Cyclic Chlorophyll Hetero‐Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems | Zendy

Kosaka Nobuo | Zendy; Tamiaki Hitoshi | Zendy

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Synthesis of a Novel Cyclic Chlorophyll Hetero‐Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems

Author(s) -

Kosaka Nobuo,

Tamiaki Hitoshi

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200400027

Subject(s) - chemistry , dyad , chlorophyll a , chlorophyll , circular dichroism , chlorin , dipole , stereochemistry , photosynthesis , photochemistry , organic chemistry , porphyrin , biochemistry , physics , acoustics

A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Q y transition dipole moments intramolecularly interact to give intense circular dichroism peaks. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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