Cover Picture: Use of Rhodium N‐Heterocyclic Carbene Complexes in Catalytic Cyclization and Hydrosilylation of 1,6‐Enynes to 2‐Methyl‐1‐silylmethylidene‐2‐cyclopentane (Eur. J. Org. Chem. 22/2003) | Zendy

Park Kang Hyun | Zendy; Kim So Yeon | Zendy; Son Seung Uk | Zendy; Chung Young Keun | Zendy

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Cover Picture: Use of Rhodium N‐Heterocyclic Carbene Complexes in Catalytic Cyclization and Hydrosilylation of 1,6‐Enynes to 2‐Methyl‐1‐silylmethylidene‐2‐cyclopentane (Eur. J. Org. Chem. 22/2003)

Author(s) -

Park Kang Hyun,

Kim So Yeon,

Son Seung Uk,

Chung Young Keun

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200390248

Subject(s) - cyclopentane , hydrosilylation , chemistry , carbene , rhodium , cyclopentanes , catalysis , medicinal chemistry , stereochemistry , organic chemistry

The cover picture shows a neutral rhodium complex [Rh(NHC)(cod)Cl] (NHC = N‐heterocyclic carbene) catalyzing the hydrosilylation/cyclization of 1,6‐enynes and HSiR 3 (R 3 = Et 3 and PhMe 2 ) to form 2‐methyl‐1‐silylmethylidene‐2‐cyclopentanes in high yields. Details are described in the Short Communication by Y. K. Chung et al. on p. 4341 ff.

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